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This is the first report describing the use of picosecond time-resolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4'-(CO2Et)(2)-2,2'-bpy)Cl2: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

Original publication

DOI

10.1039/b109919a

Type

Journal

Chemical communications (Cambridge, England)

Publication Date

02/2002

Pages

382 - 383

Addresses

School of Chemistry, University of Nottingham, University Park, Nottingham, UK NG7 2RD.