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The photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+ in CH3CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)-dppz complex with a charge separated lowest-lying excited state.

Original publication

DOI

10.1039/b200586g

Type

Journal

Chemical communications (Cambridge, England)

Publication Date

04/2002

Pages

872 - 873

Addresses

School of Chemistry, University of Nottingham, University Park, Nottingham, UK NG7 2RD.

Keywords

Rhenium, Organometallic Compounds, Spectrophotometry, Infrared, Spectroscopy, Fourier Transform Infrared, Spectrophotometry, Ultraviolet, Molecular Structure, Molecular Conformation, Kinetics, Photochemistry, Physics, Time Factors, Physical Phenomena