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We present results which suggest that the photophysics of S(1) toluene is significantly more complicated than that of the related molecules p-fluorotoluene or p-difluorobenzene. We have measured a range of photoelectron spectra for a number of S(1) internal energies, on different time scales and at different temperatures, in an attempt to unravel the competing processes, but the final conclusion remains outstanding.

Original publication

DOI

10.1063/1.2126974

Type

Journal

The Journal of chemical physics

Publication Date

11/2005

Volume

123

Addresses

School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom.